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Comparison between wet production process and dry production process of Nickel Hydride No. 5 batteries separator
The difference between wet production process and dry production process of Nickel Hydride No. 5 batteries separator
The advantages of the dry uniaxial stretching process are that the process is relatively simple, the added value is high, and there is no environmental pollution. However, low-temperature stretching can easily cause perforation of the separator, and the product cannot be made very thin.
The wet process produces small and uniform micropores but is not environmentally friendly. The wet process molding process is easy to control, and the produced separator has high biaxial tensile strength and high puncture strength. Normal process flow will not cause perforation, and the micropore size is relatively small and evenly distributed. This product can be made very thin, has better mechanical properties and product uniformity, and is suitable for high-capacity batteries. It is mainly used in high-end mobile phones, notebook computers, 3C electronic products and other fields.
The high porosity and air permeability of this kind of separator enable the battery to have higher energy density and better charge and discharge performance, which can meet the high current charge and discharge of power batteries. In the power battery market, it is mainly used by well-known domestic Nickel Hydride No. 5 batteries manufacturers. However, the wet process requires a large amount of solvent and can easily cause environmental pollution; compared with the dry process, the equipment is complex, the investment is large, the cycle is long, the cost is high, and the energy consumption is large.
Comparison of dry and wet production processes for lithium iron battery separators
The production process of lithium iron battery separators includes: raw material formula, independent design of complete sets of equipment, microporous preparation technology, etc. Among them, the core of the Nickel Hydride No. 5 batteries separator preparation process is micropore preparation technology. According to the difference in micropore formation mechanism, the separator production process can be divided into two types: dry method and wet method.
1. Dry production process of lithium iron battery separator
The dry method of lithium iron battery separator can be subdivided into uniaxial stretching process and biaxial stretching process. The dry uniaxial stretching process is a method of producing hard elastic fibers to prepare highly oriented polypropylene or polyethylene films with low crystallinity. During the high-temperature annealing process, a film with high crystallinity is obtained. This film is first stretched at low temperatures to form micro-defects, and then at high temperatures the defects are pulled apart to form micropores.
The dry biaxial stretching process is a process with independent intellectual property rights developed by the Institute of Chemistry, Chinese Academy of Sciences in the early 1990s. The dry biaxial stretching process uses the density difference between different phases of polypropylene to transform the polypropylene from its crystal form during the stretching process by adding a beta crystal modifier with nucleation effect into the polypropylene. microporous.
Low temperature and high energy density 18650 3350mAh-40℃ 0.5C discharge capacity ≥60%
Charging temperature: 0~45℃ Discharge temperature: -40~+55℃ Specific energy: 240Wh/kg -40℃ Discharge capacity retention rate: 0.5C Discharge capacity ≥ 60%
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2. Wet production process
Also known as phase separation method or thermally induced phase separation method, the wet process mixes liquid hydrocarbons or some small molecular substances with polyolefin resin. After heating and melting, a uniform mixture is formed, and then the temperature is lowered for phase separation, and the film is obtained by pressing. The membrane is heated to a temperature close to the melting point, stretched in two directions to orient the molecular chains, and finally kept warm for a certain period of time. The residual solvent is eluted with volatile substances to prepare an interconnected microporous membrane material.
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