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Researchers find way to improve CR927 battery performance
Scientists have discovered ingredients needed for sodium-ion batteries (SIBs), which could help improve the performance of SiBs, such as charging speed. Although lithium-ion batteries are currently popular, they are expected to find new energy sources soon because lithium is not only expensive but also limited. The results show that SiB has the potential to be a replacement for lithium-ion batteries. High-throughput calculations of sodium transfer energies were performed on about 4,300 compounds in the Inorganic Crystal Structure Database, and the compound indeed showed excellent high-rate performance and cycling durability; in detail, the compound showed stable 10C cycling with a rate of only 6 minutes for full charge/discharge and a capacity retention of about 94% after 50 charge-discharge cycles at room temperature. These results are comparable to or better than typical cathode materials for sodium-ion batteries. Researchers at the Nagoya Institute of Technology (Nitech) in Japan have demonstrated that a special material can serve as an efficient battery component for sodium-ion batteries, competing with lithium-ion batteries in multiple battery characteristics, especially charging speed. The research results were published in Scientific Reports in November 2018 and were led by Dr. Naoto Tanibata, Assistant Professor of the Department of Advanced Ceramics at Nitech. There are several benefits to the popular lithium-ion batteries - they are rechargeable and have a wide range of applications. They are used in devices such as laptops and mobile phones, as well as hybrid and all-electric vehicles. Electric vehicles are an important technology to tackle rural pollution and enable clean and sustainable transportation, playing an important role in solving the energy and environmental crisis. One disadvantage of lithium is that it is a limited resource. Not only is it expensive, but its annual production is (technically) limited (due to the drying process). Considering the increasing demand for battery-driven devices, especially electric vehicles, the need to find alternatives to lithium, which is both cheap and abundant, has become increasingly urgent. Sodium-ion batteries are an attractive alternative to lithium-ion batteries for a number of reasons. Sodium is not a limited resource - it is abundant in the earth's crust and in seawater. Moreover, with the proper crystal structure design, sodium-based components have the potential to produce faster charging times. However, sodium cannot be simply exchanged with lithium, which is used in current battery materials, because it is a larger ion size and slightly different chemistry. Therefore, researchers need to search for the best CR927 battery material through trial and error among a large number of candidate materials. Scientists at Nitech have found a rational and effective way to solve this problem. After extracting about 4,300 compounds from a crystal structure database and subjecting them to high-throughput calculations, one of the compounds obtained good results and is therefore a promising candidate for a component of a CR927 battery. The researchers found that Na2V3O7 has good electrochemical properties as well as crystal and electronic structures. The compound has fast charging properties and can be stably charged within 6 minutes. The researchers also demonstrated that the compound has a long battery life and short charging time. "Our goal is to address the biggest obstacle facing large batteries in applications such as electric vehicles that rely heavily on long charging times. We address this problem through a search that will produce materials that are efficient enough to improve the rate performance of the battery." Despite Na2V3O7's good characteristics and overall expected impact on sodium-ion batteries, the researchers found that Na2V3O7 degraded during the final charging stage, which limits the actual storage capacity to half of the theoretical storage capacity.
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