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Due to the high energy density of lithium batteries, in the overcharged state, the energy will be excess when the battery temperature rises, so the electrolyte decomposes to produce gas, which can easily increase the internal pressure and cause the risk of spontaneous combustion or rupture; conversely, in the overdischarged state, The decomposition of the electrolyte causes the battery characteristics and durability to deteriorate, reducing the number of recharges and shortening the battery life. Therefore, the protection of lithium batteries is very important. Lithium battery applications must have battery protection chips to prevent battery overcharge, overdischarge and overcurrent.
lithium battery
The design of lithium battery protection circuit is very important. However, the lithium battery protection circuit will increase the additional loss of battery energy and reduce the battery's application time. This requires the lithium battery protection circuit to achieve low power consumption with high precision. In addition to completing basic functions such as overcharge protection, over-discharge protection and over-current protection, a lithium battery protection chip must also meet the following requirements - this is also the goal of the chip designed in this article.
(1) Ultra-low power consumption. When the lithium battery protection circuit is working, the power consumption it consumes is the loss of the battery. Therefore, we need to minimize the power consumption of the lithium battery protection circuit.
(2) Highly accurate voltage detection. In order for the lithium battery protection circuit to respond correctly to different working states of the battery, the protection circuit must be able to accurately detect voltage parameters such as overcharge protection voltage and over-discharge protection voltage.
(3) Work correctly under a wide voltage range. Since the power supply voltage of the lithium battery protection circuit is the battery voltage, and the battery voltage can float within a wide range, the lithium battery protection circuit is required to work correctly within this voltage range.
Lithium battery protection circuit scheme
Among the various types of batteries currently in use, lithium batteries (also known as lithium-ion secondary batteries or lithium-ion batteries) are a new type of power source that have only been developed in the past decade. Lithium batteries are different from general chemical power sources. The charging and discharging process is achieved through the insertion and deintercalation of lithium ions in the positive and negative electrodes of the battery. The negative electrode of a lithium battery is a carbon material, such as graphite; the positive electrode is a lithium-containing transition metal oxide, such as lithium cobalt oxide (LiC002). Moreover, both the positive and negative electrode materials of lithium batteries use lithium ion intercalation compounds with a layered structure in which lithium ions can be freely inserted and detached. The lithium ions between the layers will undergo an electrochemical reaction in an appropriate electrolyte. During charging, lithium ions are extracted from the positive electrode lattice driven by the external electric field, pass through the electrolyte, and are embedded in the negative electrode lattice. The process during discharge is exactly the opposite. Lithium ions return to the positive electrode, and electrons reach the positive electrode through the external circuit to recombine with the lithium ions.
Compared with commonly used nickel-cadmium and nickel-hydrogen batteries, lithium batteries have many superior characteristics, mainly in the following aspects:
(1) The power supply voltage of lithium batteries is high, generally 3.6V, which is about three times the voltage of nickel-cadmium batteries and nickel-metal hydride batteries. For electronic equipment with higher power supply voltage requirements, the number of series cells required in the battery pack can also be greatly reduced. Therefore, the lithium battery used in combination can easily obtain higher voltage.
(2) High specific energy, that is, lithium batteries of the same weight provide higher energy than other batteries. The specific energy of lithium batteries is generally 2 to 3 times that of nickel-cadmium batteries and nickel-metal hydride batteries. Therefore, it is beneficial to reduce the size and weight of portable electronic devices.
(3) No memory effect. Nickel-cadmium batteries and nickel-metal hydride batteries have memory effects and must be discharged regularly, otherwise the batteries will fail due to the memory effect. Lithium batteries have no memory effect and can be charged directly regardless of the remaining power. This allows the lithium battery performance to be fully utilized.
(4) Long service life. Lithium batteries use carbon negative electrodes. The carbon negative electrodes do not generate metallic lithium during the charge and discharge process, thus preventing the battery from being damaged by a short circuit of internal metallic lithium. At present, the cycle life of lithium batteries can reach more than 5,000 times, which is much higher than other types of batteries.
(5) The working environment temperature range is wide, and it can generally work between -30℃ and 0℃, and has excellent high and low temperature discharge performance.
(6) Low self-discharge rate. Self-discharge rate, also known as charge retention rate, refers to how much the battery automatically discharges when it is not in use. The self-discharge rate of lithium batteries is 2% to 5%, that of nickel-cadmium batteries is between 25% and 30%, and that of nickel-metal hydride batteries is between 30% and 35%. Therefore, lithium batteries retain charge for the longest time under the same environment.
(7) Lithium batteries do not contain any toxic elements such as mercury and cadmium and are truly green and environmentally friendly batteries.
Based on the above advantages, lithium batteries are widely used in portable electronic devices. On the other hand, lithium batteries have high energy density, making it difficult to ensure battery safety. Specifically, in the overcharge state, the electrolyte will be decomposed, causing the temperature and pressure inside the battery to rise; in the overdischarge state, the electrolytic material in the negative electrode, copper, will melt and cause an internal short circuit, causing the temperature to rise: When the external circuit is short-circuited or the discharge current Chapter 1 Introduction 3 is too large, due to the characteristics of high internal resistance, the internal power consumption of the battery will increase and the temperature will also rise, which may cause oxidation or decomposition of the electrolyte, resulting in shortened lithium battery life. In addition, if the lithium battery is excessively discharged, the electrolyte in the battery will change, and the number of recharge cycles will be reduced, thereby affecting the service life of the lithium battery.
Since lithium batteries have the shortcomings analyzed above, a protection circuit must be added to the application of lithium batteries. The basic functions of the protection circuit must also correspond to the above shortcomings, so we require the lithium battery power protection chip to be able to achieve the following most basic functions: overcharge protection, over-discharge protection, over-current protection and short-circuit protection. From the above application requirements of lithium batteries, it can be seen that in order to increase the service life of lithium batteries and ensure the safe use of batteries, lithium battery protection circuits need to have the following functions:
(1) If the charging voltage exceeds the maximum allowed value of the battery, a battery discharge circuit can be provided.
(2) If the discharge voltage is lower than the minimum allowed value of the battery, a battery charging circuit can be provided. then disconnect the battery from the external circuit, and then disconnect the battery from the external circuit, and
(3) If the charging and discharging current of the battery is greater than the limit value, cut off the connection between the battery and the external circuit.
(4) When the battery returns to normal state, the protection circuit should be able to release the protection state accordingly so that the battery can continue to work normally.
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