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The composition of internal resistance of 12V23A battery
1. Composition of internal resistance of 12V23A battery
Theoretically, as with ohmic resistance (ir), both active and concentration polarization can be understood as the components of battery resistance, in other words, reactive and differential impedance. When building complex mathematical analysis models, the magnitude of active polarization and concentration polarization should be used.
Internal impedance consists of
1. Ion resistance
Electrolyte inside the diaphragm
Influencing factors
12V23A battery electrolyte conductivity, diaphragm area, thickness, porosity, Gurley index
2. The electrolyte inside the positive electrode
Influencing factors
12V23A battery electrolyte conductivity, positive stage thickness, thin layer thickness, porosity, roughness index
3. The electrolyte inside the positive electrode
Influencing factors
12V23A battery electrolyte conductivity, positive stage thickness, thin layer thickness, porosity, roughness index
2. Electronic resistance
1. Two electrode active materials
Influencing factors
Conductivity, thickness, total area
2. Current collector (copper foil and aluminum foil)
Influencing factors
Collect liquid thickness, total width, length, total pinna, and location
3. Wires (lugs, poles, inner conductive connecting components)
Influencing factors
Conductivity
3. Resistance of active material and collection liquid
Positive chemicals and aluminum platinum
Negative chemicals and copper cans
Photocatalytic resistance of rechargeable batteries
The power level equivalent circuit diagram composed of current characteristic impedance rb, double-layer capacitance cd, electrochemical corrosion resistance rct and its outer diffusion resistance rw is given. Generally speaking, during the entire process of lithium-ion battery placement and sliding cycle system, the rb value conversion is usually not large, but the changes in cd and rct are significant.
The characteristic impedance of rechargeable batteries is mainly electrochemical corrosion resistance, but the relative impedance of ohmic characteristics is small. from the chart below. As the temperature decreases, the characteristic impedance of the rechargeable battery increases slowly, then decreases to 0c, the characteristic impedance rate increases, and the trend of negative characteristic impedance is similar.
In fact, during the entire cycle of the rechargeable battery, the negative electrode characteristic impedance accounts for a key part of the entire rechargeable battery's characteristic impedance, which is only slightly smaller than the entire rechargeable battery. Therefore, the detection of negative electrode resistance is of great significance in the entire electrical level process.
Communication AC internal resistance and DC internal resistance
In fact, the DC internal resistance (DCR) of rechargeable batteries is usually detected by communication and exchange methods in enterprises. The IEC standard also requires DC resistance detection of rechargeable batteries.
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